For Excel 2007
If you are using Excel 2007 then you can download the Microsoft Save as PDF plug-in to save workbook as PDF
For Excel 2010
In Excel 2010, new feature has been added to save Excel files as PDF format using SAVE AS feature.
Steps to Save workbook as PDF.
1. Open a workbook
2. On the File tab, click Save As.
3. Select PDF from dropdown list.
4. Click Options
5. Select option for publishing Selection, Active sheet or Entire Workbook.
6. Click OK and then click Save.
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